Factors Affecting Color Reaction When Using Colorimetric Method to Detect Water Quality

  At present, colorimetry is a method widely used in water quality detection, and it has high sensitivity. If the content of a certain substance in the water to be measured is very low, it can be detected by colorimetry after concentration, extraction, co-precipitation and other methods. Moreover, the selection of special reagents and colorimetric conditions can reduce the separation steps and accelerate the detection time of water samples. Therefore, for the detection of certain substances in water, the colorimetric method is an accurate, sensitive, simple and rapid method. But even so, there are still some factors that affect the colorimetric test results in daily life.

Colorimetric method for water quality detection

Factors affecting the color reaction of colorimetry

1. The influence of acidity in water samples

   It is a very important condition to control the acidity of the sample when using the colorimetric method to detect water quality. For example, the barium complex acid colorimetric method requires partial acid during the reaction to determine the sulfate, so that the barium complex acid can precipitate to form barium ions and The chromite ion is dissolved, but a partial alkali is required when it is filtered, so that the excess barium complexate can be precipitated again.

2. The influence of water sample temperature on color development

   The temperature of the water sample has a decisive effect on some color reactions. For example, to measure manganese by ammonium persulfate oxidation method, the color must be boiled, but the boiling time must be controlled. If the heating time is too long, the temperature rises due to the concentration of the solution, causing the ammonium persulfate to quickly decompose and the solution to fade.

Wait for the color of the sample during water quality testing

3. Sample color development time and solution color stability time

   In most color reactions, a certain period of time will elapse after adding reagents to show a stable color. Generally speaking, many items in the standard method list the color stabilization time. However, some color reactions are under specific environmental conditions in the laboratory (such as room temperature, sunlight, etc.), impurities contained in pure water and reagents can affect the color instability. For example, the dithizone method for measuring lead and mercury can fade due to sunlight.

4. The influence of interfering ions during water quality testing

   Interfering substances can form colored substances with reagents, or inhibit the color reaction between the developer and the component to be determined. For example, when other metal ions are excessively present, it can affect the measurement of lead by the dithizone method, but we can follow the standard method or Relevant guidance to take measures to eliminate interference.